A new method to synthesize N, N'-diphenyl thiourea ( DPTU) from aniline and CS 2 was developed in the presence of acidic resin as catalyst under reflux temperature for 6 h with the yield of 82.7% and the selectivity of 100%.

  • 探讨了合成二苯硫脲的新方法。以酸性树脂作催化剂在回流温度下使苯胺与CS2反应6h,二苯硫脲的收率达827%,选择性为100%。
  • 来源:互联网摘选更新时间:2025-01-20 12:31:23

  • 重点词汇
  • refluxn.逆流,退潮;
  • ofprep. 关于;属于…的;由…制成;
  • catalystn.<化>触媒,催化剂;〈比喻〉触发因素;促进因素;〈口〉有感染力的人;
  • 6num. six;
  • hn. 英语字母表的第8个字母;大写为H
  • in the presence ofadv.在面前;
  • csabbr. cours (French=course, currency, current price) (法语)过程;common steel 普通钢;communication system 通信系统;cryptographic system 加密系统;
  • theart.这个;指已提到或易领会到的人或事物;指独一无二的、正常的或不言而喻的人或事物;用以泛指;与形容词连用,指事物或统称的人;用于姓氏的复数形式前,指家庭或夫妇;(指特定用途的事物)足够,恰好;每,一;当前的,本,此;(重读,表示所指的为知名或重要的人或事物)
  • nn. 英语字母表的第14个字母;
  • acidic resin酸性树脂;
  • asadv. 同样地,一样地;例如;
  • 相关例句
1、

This mechanism can also reasonably explain the fact that only molecular ionic peak of phenyl iso-thiocyanate and naphthyl iso-thiocyanate was presented in the GC/ MS spectra of diphenylurea and diphenyl thiourea.

此机理同样能合理解释二苯脲和二萘硫脲的GC/MS谱图中只出现异氰酸苯酯和异硫氰酸萘酯分子离子峰的现象。

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2、

But the GC/ MS analysis showed that it is phenyl isocyanate. This may be due to neutral loss of aniline in the cleavage of diphenyl thiourea in GC/ MS analysis.

但用GC/MS分析该晶体为异硫氰酸苯酯,这可能是在GC/MS分析过程中二苯硫脲发生了中性丢失苯胺的缘故。

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3、

Under mild conditions, at room temperature and ambient atmosphere, diphenyl thiourea could be synthesized through the reaction of aniline and CS 2 over AlCl 3 catalyst with high yield and high selectivity.

常温常压下,用AlCl3作催化剂催化苯胺和CS2进行反应,可以高收率和高选择性地得到二苯硫脲。

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4、

However, identified by melting point, HPLC/ MS/ MS, FTIR, UV and 1H NMR analyses, the pure crystal should be diphenyl thiourea.

然而,用熔点测定、HPLC/MS/MS,FTIR,UV和1H NMR等手段对此晶体进行分析,确定其为二苯硫脲。

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5、

Neutral Loss of Aniline in GC/ MS Analysis of Diphenyl Thiourea

GC/MS解析中二苯硫脲的中性丢失

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7、

Measurement of Sodium and Potassium in 4,4'-Diamino? Diphenyl Oxide by Atomic Absorption Spectrophotometry

原子吸收法测定4,4′-二氨基二苯醚中钠和钾

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8、

Alkylation of Diphenyl Oxide Catalyzed by Ionic Liquid

离子液体催化合成烷基二苯醚

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9、

Kinetics of curing reaction of benzoxazine precursors based on diphenyl oxide resin

苯并恶嗪二苯醚树脂中间体开环固化反应动力学

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10、

Preparation of modified diphenyl oxide resin glass cloth laminated sheet

改性二苯醚树脂及其玻璃布层压板的研制

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11、

Study on cure behavior of benzoxazine based on diphenyl oxide resin

苯并恶嗪二苯醚树脂的固化行为研究

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12、

Most of thorium was removed from the title ore in the 6V/ V% HCl solution using cupferron choroform, and uranium and remainder thorium eliminated from 10 V/ V% HCl solution by diphenyl guanidine ( DPG) Arsenazo ⅲ n-butanol.

试验了在6%(V/V)HCl中用铜铁试剂氯仿除去大部分钍,在10%HCl(V/V)中用二苯胍偶氮胂Ⅲ正丁醇除尽钍铀;

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13、

The electrochemical behaviour and the current property of the entitled complex have been investigated in NH_3 · H_20-NH_4Cl buffer solution ( pH 9. 5) containing EDTA and diphenyl guanidine. The mechanism of related reactions has been discussed.

本文研究了铍(Ⅱ)-钍试剂Ⅱ在EDTA、二苯胍、氨-铵缓冲溶液(pH9.5)中的电极行为和电流性质,并对有关机理进行了探讨。

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14、

Diphenyl guanidine has been prepared by using of Fe2 O3 as catalyst and70% ethanol as solvent, and simultaneously the by-product H2S is used to prepare thiourea.

本文提出了在70%乙醇溶剂中以氧化铁作为触煤合成二苯胍,同时回收副产硫化氢合成硫脲的联合制备方法。

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15、

Studies on Extraction Spectrophotometry of Ternary Molybdenum(ⅵ) 4 ( 5 Bromo 2 Thiazolylazo) Pyrocatechol Diphenyl Guanidine Ion Associate

钼(Ⅵ)-4-(5-溴-2-噻唑偶氮)邻苯二酚-二苯胍三元离子缔合物的萃取分光光度研究

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16、

Development of Synthetic Technique for Diphenyl Guanidine

二苯胍合成技术进展

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17、

It can further reacts with diphenyl guanidine to form a stable, neutral, violet-red 1: 2:1 ternary ionic-associate complex.

它可与二苯胍进一步反应形成电中性的稳定紫红色1∶2∶1三元离子缔合络合物。

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18、

Development of Diphenyl Guanidine

二苯胍的研制

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19、

The novel points of the article contain three aspects in the following: ( 1) With thiol sealing end polysulfide, poly tetrahydrofuran ether ( PTMG), diphenyl methane diisocyanate ( MDI) as raw materials, to prepare polysulfide-based polyurethane composite material.

本研究的新颖点主要包含以下三方面:(1)以巯基封端聚硫橡胶(PS)、聚四氢呋喃醚(PTMG)、二苯基甲烷二异氰酸酯(MDI)为原料,合成聚硫聚氨酯复合材料。

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